Mangan(III) fluorida

Mangan(III) fluorida
Nama

Nama IUPAC Manganese(III) fluoride
Nama lain Mangan trifluorida, manganit fluorida
Penanda
Nomor CAS	7783-53-1^Y
Model 3D (JSmol)	Gambar interaktif
ChemSpider	74193^Y
Nomor EC
PubChem CID	82213
Nomor RTECS	{{{value}}}
UNII	VHG84D268X^Y
CompTox Dashboard (EPA)	DTXSID50893904
InChI InChI=1S/3FH.Mn/h31H;/q;;;+3/p-3^Y Key: SRVINXWCFNHIQZ-UHFFFAOYSA-K^Y InChI=1/3FH.Mn/h31H;/q;;;+3/p-3 Key: SRVINXWCFNHIQZ-DFZHHIFOAX
SMILES [Mn+3].[F-].[F-].[F-]
Sifat
Rumus kimia	MnF₃
Massa molar	111.938 g/mol
Penampilan	bubuk ungu-merah muda higroskopis
Densitas	3.54 g/cm³
Titik lebur	> 600 °C (1.112 °F; 873 K) (terurai)
Kelarutan dalam air	hidrolisis
Suseptibilitas magnetik (χ)	+10,500·10⁻⁶ cm³/mol
Struktur
Struktur kristal	Monoklinik, mS48
Grup ruang	C2/c, No. 15
Geometri koordinasi	oktahedral terdistorsi
Bahaya
Bahaya utama	uap beracun
Piktogram GHS
Keterangan bahaya GHS	{{{value}}}
Pernyataan bahaya GHS	H272, H301, H312, H315, H319, H332, H335
Langkah perlindungan GHS	P220, P261, P280, P301+P310, P305+P351+P338
Senyawa terkait
Anion lain	mangan(III) oksida, mangan(III) asetat
Kation lainnya	kromium(III) fluorida, besi(III) fluorida. kobalt(III) fluorida
Senyawa terkait	mangan(II) fluorida, mangan(IV) fluorida
Kecuali dinyatakan lain, data di atas berlaku pada suhu dan tekanan standar (25 °C [77 °F], 100 kPa).
N verifikasi (apa ini ^YN ?)
Referensi

Chemical compoundTemplat:SHORTDESC:Chemical compound

Mangan(III) fluorida (juga dikenal sebagai Mangan trifluorida ) adalah senyawa anorganik dengan rumus MnF₃. Padatan merah/keunguan ini digunakan untuk mengubah hidrokarbon menjadi fluorokarbon, yaitu zat fluorinasi.^[1] Ini membentuk hidrat dan banyak turunannya.

Sintesis, struktur, dan reaksi

MnF₃ dapat dibuat dengan mereaksikan larutan MnF₂ dalam hidrogen fluorida dengan fluor:^[2]

MnF₂ + 0.5 F₂ → MnF₃

Ini juga dapat dibuat dengan mereaksikan unsur fluorin dengan mangan(II) halida pada ~250 °C.^[3]

Struktur

Seperti vanadium(III) fluorida, MnF₃ menampilkan pusat logam oktahedral dengan jarak ikatan MF rata-rata yang sama. Namun, dalam senyawa Mn, terdistorsi (dan karenanya sel satuan monoklinik dengan sel simetri yang lebih tinggi) karena efek Jahn-Teller , dengan pasangan jarak Mn-F 1,79, 1,91, 2,09 Å.^[4]^[5]^[6]

Hidrat MnF₃^.3H₂O diperoleh dengan kristalisasi MnF₃ dari asam fluorida. Hidrat tersedia sebagai dua polimorf, dengan grup ruang P2₁/c dan P2₁/a. Masing-masing terdiri dari garam Mn(H₂O)₄F₂]⁺[Mn(H₂O)₂F₄]⁻ ).^[7]

Reaksi

MnF₃ bersifat asam Lewis dan membentuk berbagai turunan. Salah satu contohnya adalah K₂MnF₃(SO₄).^[8] MnF₃ bereaksi dengan natrium fluorida menghasilkan heksafluorida oktahedral:^[3]

3NaF + MnF₃ → Na₃MnF₆

Reaksi terkait garam dari anion MnF₅²⁻ atau MnF₄⁻. Anion ini masing-masing mengadopsi struktur rantai dan lapisan, dengan menjembatani fluorida. Mangan tetap 6 koordinat, oktahedral, dan trivalen di semua bahan ini.^[3]

Mangan(III) fluorida memfluorinasi senyawa organik termasuk hidrokarbon aromatik,^[9] siklobutena,^[10] dan fullerena.^[11]

Saat pemanasan, MnF₃ terurai menjadi mangan(II) fluorida.^[12]^[13]

MnF₃ merupakan sumber kompleks MnCl₃ melalui reaksi dengan bismut triklorida.^[14]

Referensi

↑ Burley, G. A.; Taylor, R. (2004). "Manganese(III) Fluoride". Encyclopedia of Reagents for Organic Synthesis. J. Wiley & Sons. doi:10.1002/047084289X.rn00411.
↑ 3, MnF4 and hexafluoromanganete(IV) salts of alkali cations"},"author":{"wt":"Z. Mazej"},"journal":{"wt":"Journal of Fluorine Chemistry"},"year":{"wt":"2002"},"volume":{"wt":"114"},"issue":{"wt":"1"},"pages":{"wt":"75–80"},"doi":{"wt":"10.1016/S0022-1139(01)00566-8"}},"i":0}}]}' id="mwoA"/>Z. Mazej (2002). "Room temperature syntheses of MnF₃, MnF₄ and hexafluoromanganete(IV) salts of alkali cations". Journal of Fluorine Chemistry. 114 (1): 75–80. doi:10.1016/S0022-1139(01)00566-8.
1 2 3 Inorganic chemistry, Catherine E. Housecroft, A.G. Sharpe, pp.711-712, section Manganese (III) , googlebooks link
↑ Wells, A.F. (1984) Structural Inorganic Chemistry, Oxford: Clarendon Press. ISBN 0-19-855370-6.
↑ Hepworth, M. A.; Jack, K. H.; Nyholm, R. S. (1957). "Interatomic Bonding in Manganese Trifluoride". Nature. 179 (4552): 211–212. Bibcode:1957Natur.179..211H. doi:10.1038/179211b0. S2CID 4208409.
↑ 3"},"author1":{"wt":"M. A. Hepworth"},"author2":{"wt":"K. H. Jack"},"journal":{"wt":"Acta Crystallographica"},"year":{"wt":"1957"},"volume":{"wt":"10"},"issue":{"wt":"5"},"pages":{"wt":"345–351"},"doi":{"wt":"10.1107/S0365110X57001024"}},"i":0}}]}' id="mwzA"/>M. A. Hepworth; K. H. Jack (1957). "The Crystal Structure of Manganese Trifluoride, MnF₃". Acta Crystallographica. 10 (5): 345–351. doi:10.1107/S0365110X57001024.
↑ Molinier Michel; Massa Werner (1992). "Structures of two polymorphs of MnF3·3H2O". Journal of Fluorine Chemistry. 57 (1–3): 139–146. doi:10.1016/S0022-1139(00)82825-0.
↑ Bhattacharjee, M. N; Chaudhuri, M. K. (1990). Dipotassium Trifluorosulfatomanganate(III). Inorganic Syntheses. Vol. 27. hlm. 312–313. doi:10.1002/9780470132586.ch61. ISBN 9780470132586.
↑ Fluorination of p-chlorobenzotrifluoride by manganese trifluoride Diarsipkan 2011-08-23 di Wayback Machine. A. Kachanov, V. Kornilov, V.Belogay , Fluorine Notes :Vol. 1 (1) November–December 1998 , via notes.fluorine1.ru
↑ "Fluorination of Fluoro-Cyclobutene with High-Valency Metal Fluoride". Journal of Fluorine Chemistry. 127: 79–84. 2006. doi:10.1016/j.jfluchem.2005.10.007.
↑ 60 Modifications by Crystalline Manganese Trifluoride"},"journal":{"wt":"Physics of the Solid State"},"volume":{"wt":"44"},"issue":{"wt":"4"},"year":{"wt":"2002"},"pages":{"wt":"629–630"},"authors":{"wt":"V. É. Aleshina, A. Ya. Borshchevskii, E. V. Skokan, I. V. Arkhangel'skii, A.V. Astakhov, N.B. Shustova"},"doi":{"wt":"10.1134/1.1470543"},"bibcode":{"wt":"2002PhSS...44..629A"},"s2cid":{"wt":"94250136"}},"i":0}}]}' id="mwAQ4"/>"Fluorination of the Cubic and Hexagonal C₆₀ Modifications by Crystalline Manganese Trifluoride". Physics of the Solid State. 44 (4): 629–630. 2002. Bibcode:2002PhSS...44..629A. doi:10.1134/1.1470543. S2CID 94250136.
↑ Chisholm, Hugh, ed. (1911). "Manganese § Manganic Salts" . Encyclopædia Britannica. Vol. 17 (Edisi 11). Cambridge University Press. hlm. 570.
↑ In situ time-resolved X-ray diffraction study of manganese trifluoride thermal decomposition , J.V. Raua, V. Rossi Albertinib, N.S. Chilingarova, S. Colonnab, U. Anselmi Tamburini, Journal of Fluorine Chemistry 4506 (2001) 1–4 , online version
↑ Nachtigall, Olaf; Pataki, Astrid; Molski, Matthias; Lentz, Dieter; Spandl, Johann (2015). "Solvates of Manganese Trichloride Revisited - Synthesis, Isolation, and Crystal Structure of MnCl3(THF)3". Zeitschrift für Anorganische und Allgemeine Chemie. 641 (6): 1164–1168. doi:10.1002/zaac.201500106.

[eros-1] Burley, G. A.; Taylor, R. (2004). "Manganese(III) Fluoride". Encyclopedia of Reagents for Organic Synthesis. J. Wiley & Sons. doi:10.1002/047084289X.rn00411.

[mad-2] 3</sub>, MnF<sub>4</sub> and hexafluoromanganete(IV) salts of alkali cations"},"author":{"wt":"Z. Mazej"},"journal":{"wt":"Journal of Fluorine Chemistry"},"year":{"wt":"2002"},"volume":{"wt":"114"},"issue":{"wt":"1"},"pages":{"wt":"75–80"},"doi":{"wt":"10.1016/S0022-1139(01)00566-8"}},"i":0}}]}' id="mwoA"/>Z. Mazej (2002). "Room temperature syntheses of MnF₃, MnF₄ and hexafluoromanganete(IV) salts of alkali cations". Journal of Fluorine Chemistry. 114 (1): 75–80. doi:10.1016/S0022-1139(01)00566-8.

[shap-3] 1 2 3 Inorganic chemistry, Catherine E. Housecroft, A.G. Sharpe, pp.711-712, section Manganese (III) , googlebooks link

[4] Wells, A.F. (1984) Structural Inorganic Chemistry, Oxford: Clarendon Press. ISBN 0-19-855370-6.

[5] Hepworth, M. A.; Jack, K. H.; Nyholm, R. S. (1957). "Interatomic Bonding in Manganese Trifluoride". Nature. 179 (4552): 211–212. Bibcode:1957Natur.179..211H. doi:10.1038/179211b0. S2CID 4208409.

[6] 3</sub>"},"author1":{"wt":"M. A. Hepworth"},"author2":{"wt":"K. H. Jack"},"journal":{"wt":"Acta Crystallographica"},"year":{"wt":"1957"},"volume":{"wt":"10"},"issue":{"wt":"5"},"pages":{"wt":"345–351"},"doi":{"wt":"10.1107/S0365110X57001024"}},"i":0}}]}' id="mwzA"/>M. A. Hepworth; K. H. Jack (1957). "The Crystal Structure of Manganese Trifluoride, MnF₃". Acta Crystallographica. 10 (5): 345–351. doi:10.1107/S0365110X57001024.

[7] Molinier Michel; Massa Werner (1992). "Structures of two polymorphs of MnF3·3H2O". Journal of Fluorine Chemistry. 57 (1–3): 139–146. doi:10.1016/S0022-1139(00)82825-0.

[8] Bhattacharjee, M. N; Chaudhuri, M. K. (1990). Dipotassium Trifluorosulfatomanganate(III). Inorganic Syntheses. Vol. 27. hlm. 312–313. doi:10.1002/9780470132586.ch61. ISBN 9780470132586.

[9] Fluorination of p-chlorobenzotrifluoride by manganese trifluoride Diarsipkan 2011-08-23 di Wayback Machine. A. Kachanov, V. Kornilov, V.Belogay , Fluorine Notes :Vol. 1 (1) November–December 1998 , via notes.fluorine1.ru

[10] "Fluorination of Fluoro-Cyclobutene with High-Valency Metal Fluoride". Journal of Fluorine Chemistry. 127: 79–84. 2006. doi:10.1016/j.jfluchem.2005.10.007.

[11] 60</sub> Modifications by Crystalline Manganese Trifluoride"},"journal":{"wt":"Physics of the Solid State"},"volume":{"wt":"44"},"issue":{"wt":"4"},"year":{"wt":"2002"},"pages":{"wt":"629–630"},"authors":{"wt":"V. É. Aleshina, A. Ya. Borshchevskii, E. V. Skokan, I. V. Arkhangel'skii, A.V. Astakhov, N.B. Shustova"},"doi":{"wt":"10.1134/1.1470543"},"bibcode":{"wt":"2002PhSS...44..629A"},"s2cid":{"wt":"94250136"}},"i":0}}]}' id="mwAQ4"/>"Fluorination of the Cubic and Hexagonal C₆₀ Modifications by Crystalline Manganese Trifluoride". Physics of the Solid State. 44 (4): 629–630. 2002. Bibcode:2002PhSS...44..629A. doi:10.1134/1.1470543. S2CID 94250136.

[12] Chisholm, Hugh, ed. (1911). "Manganese § Manganic Salts" . Encyclopædia Britannica. Vol. 17 (Edisi 11). Cambridge University Press. hlm. 570.

[13] In situ time-resolved X-ray diffraction study of manganese trifluoride thermal decomposition , J.V. Raua, V. Rossi Albertinib, N.S. Chilingarova, S. Colonnab, U. Anselmi Tamburini, Journal of Fluorine Chemistry 4506 (2001) 1–4 , online version

[14] Nachtigall, Olaf; Pataki, Astrid; Molski, Matthias; Lentz, Dieter; Spandl, Johann (2015). "Solvates of Manganese Trichloride Revisited - Synthesis, Isolation, and Crystal Structure of MnCl3(THF)3". Zeitschrift für Anorganische und Allgemeine Chemie. 641 (6): 1164–1168. doi:10.1002/zaac.201500106.

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l b s Senyawa mangan
Mangan(-I)	MnH(CO)₅
Mangan(0)	Mn₂(CO)₁₀
Mangan(I)	(C₅H₄CH₃)Mn(CO)₃
Mangan(II)	MnC₂O₄ MnO Mn₃(PO₄)₂ MnS MnSe MnTe Mn(NO₃)₂ MnCO₃ MnCl₂ MnSO₄ MnF₂ MnBr₂ MnI₂ MnTiO₃ MnMoO₄ Mn(CH₃COO)₂ Mn(OH)₂ MnSe₂ Mn(ClO₃)₂ Mn(C₅H₅)₂ Mn(C₃H₅O₃)₂
Mangan(II,III)	Mn₃O₄
Mangan(II,IV)	Mn₅O₈
Mangan(III)	MnCl₃ Mn₂O₃ MnF₃ K₆Mn₂O₆ MnAs
Mangan(IV)	MnS₂ MnCl₄ MnO₂ MnF₄ MnSi MnGe
Mangan(V)	K₃MnO₄
Manganese(VI)	H₂MnO₄ MnO₃ Na₂MnO₄ K₂MnO₄
Mangan(VII)	Mn₂O₇ HMnO₄ NaMnO₄ KMnO₄ NH₄MnO₄ AgMnO₄ Ca(MnO₄)₂ Ba(MnO₄)₂

l b s Senyawa fluorin
Senyawa biner	AcF₃ AgF AgF₂ Ag₂F AlF₃ AmF₃ AmF₄ AsF₃ AsF₅ AuF₃ BF₃ B₂F₄ BaF₂ BeF₂ BiF₃ BiF₅ BrF₃ BrF₅ CF₄ C₂F₆ CaF₂ CdF₂ CeF₃ ClF₃ ClF₅ CoF₂ CoF₃ CrF₂ CrF₃ CrF₄ CrF₅ CrF₆ CsF CuF DyF₃ ErF₃ EuF₂ EuF₃ DF HF FI KF LiF NaF RbF TlF FeF₂ FeF₃ HgF₂ Hg₂F₂ KrF₂ LaF₃ LuF₃ MgF₂ MnF₂ MoF₄ MoF₅ MoF₆ NiF₂ F₂O F₂O₄ PbF₂ PbF₄ PdF₂ SnF₂ SrF₂ XeF₂ ZnF₂ ZrF₂ GaF₃ GdF₃ HoF₃ InF₃ MnF₃ F₃N NbF₄ NbF₅ NdF₃ F₃P PrF₃ PuF₃ SbF₃ ScF₃ SmF₃ TbF₃ TiF₃ TiF₄ TlF₃ TmF₃ UF₃ VF₃ YF₃ YbF₃ GeF₄ HfF₄ F₄N₂ PuF₄ SF₄ SeF₄ SiF₄ SnF₄ TeF₄ ThF₄ UF₄ VF₄ WF₄ XeF₄ ZrF₄ IF₅ PF₅ SbF₅ TaF₅ UF₅ VF₅ WF₅ OsF₆ PtF₆ ReF₆ SF₆ SeF₆ TeF₆ UF₆ WF₆ XeF₆ IF₇ ReF₇ IrF₃ IrF₆ OsF₄ OsF₅ PmF₃ PrF₄ PuF₆ ReF₄ ReF₅ RhF₆ RuF₃ RuF₄ RuF₅ RuF₆ TcF₅ TcF₆ VF₂ YbF₂
Lain-lain	AgBF₄ AgPF₆ Cs₂AlF₅ K₃AlF₆ Na₃AlF₆ KAsF₆ LiAsF₆ NaAsF₆ HBF₄ KBF₄ LiBF₄ NaBF₄ RbBF₄ Ba(BF₄)₂ Ni(BF₄)₂ Pb(BF₄)₂ Sn(BF₄)₂ BaClF BaSiF₆ BaGeF₆ BrOF₃ BrO₂F CBrF₃ CBr₂F₂ CBr₃F CClF₃ CCl₂F₂ CCl₃F CFN CF₂O CF₃I CHF₃ CH₂F₂ CH₃F C₂Cl₃F₃ C₂H₃F C₆H₅F C₇H₅F₃ C₁₅F₃₃N ClFO₂ CrFO₄ CrF₂O₂ CsBF₄ NH₄F FNO FNO₂ FNO₃ KHF₂ NaHF₂ ThOF₂ NH₅F₂ F₂OS F₃OP F₃PS HPF₆ HSbF₆ KPF₆ KSbF₆ LiPF₆ NaPF₆ NaSbF₆ Na₂SiF₆ Na₂TiF₆ Na₂ZrF₆ TlPF₆ IOF₃ K₂NbF₇ K₂TaF₇ IO₃F
Rumus kimia

l b s Senyawa mangan
Mangan(-I)	MnH(CO)₅
Mangan(0)	Mn₂(CO)₁₀
Mangan(I)	(C₅H₄CH₃)Mn(CO)₃
Mangan(II)	MnC₂O₄ MnO Mn₃(PO₄)₂ MnS MnSe MnTe Mn(NO₃)₂ MnCO₃ MnCl₂ MnSO₄ MnF₂ MnBr₂ MnI₂ MnTiO₃ MnMoO₄ Mn(CH₃COO)₂ Mn(OH)₂ MnSe₂ Mn(ClO₃)₂ Mn(C₅H₅)₂ Mn(C₃H₅O₃)₂
Mangan(II,III)	Mn₃O₄
Mangan(II,IV)	Mn₅O₈
Mangan(III)	MnCl₃ Mn₂O₃ MnF₃ K₆Mn₂O₆ MnAs
Mangan(IV)	MnS₂ MnCl₄ MnO₂ MnF₄ MnSi MnGe
Mangan(V)	K₃MnO₄
Manganese(VI)	H₂MnO₄ MnO₃ Na₂MnO₄ K₂MnO₄
Mangan(VII)	Mn₂O₇ HMnO₄ NaMnO₄ KMnO₄ NH₄MnO₄ AgMnO₄ Ca(MnO₄)₂ Ba(MnO₄)₂

l b s Senyawa fluorin
Senyawa biner	AcF₃ AgF AgF₂ Ag₂F AlF₃ AmF₃ AmF₄ AsF₃ AsF₅ AuF₃ BF₃ B₂F₄ BaF₂ BeF₂ BiF₃ BiF₅ BrF₃ BrF₅ CF₄ C₂F₆ CaF₂ CdF₂ CeF₃ ClF₃ ClF₅ CoF₂ CoF₃ CrF₂ CrF₃ CrF₄ CrF₅ CrF₆ CsF CuF DyF₃ ErF₃ EuF₂ EuF₃ DF HF FI KF LiF NaF RbF TlF FeF₂ FeF₃ HgF₂ Hg₂F₂ KrF₂ LaF₃ LuF₃ MgF₂ MnF₂ MoF₄ MoF₅ MoF₆ NiF₂ F₂O F₂O₄ PbF₂ PbF₄ PdF₂ SnF₂ SrF₂ XeF₂ ZnF₂ ZrF₂ GaF₃ GdF₃ HoF₃ InF₃ MnF₃ F₃N NbF₄ NbF₅ NdF₃ F₃P PrF₃ PuF₃ SbF₃ ScF₃ SmF₃ TbF₃ TiF₃ TiF₄ TlF₃ TmF₃ UF₃ VF₃ YF₃ YbF₃ GeF₄ HfF₄ F₄N₂ PuF₄ SF₄ SeF₄ SiF₄ SnF₄ TeF₄ ThF₄ UF₄ VF₄ WF₄ XeF₄ ZrF₄ IF₅ PF₅ SbF₅ TaF₅ UF₅ VF₅ WF₅ OsF₆ PtF₆ ReF₆ SF₆ SeF₆ TeF₆ UF₆ WF₆ XeF₆ IF₇ ReF₇ IrF₃ IrF₆ OsF₄ OsF₅ PmF₃ PrF₄ PuF₆ ReF₄ ReF₅ RhF₆ RuF₃ RuF₄ RuF₅ RuF₆ TcF₅ TcF₆ VF₂ YbF₂
Lain-lain	AgBF₄ AgPF₆ Cs₂AlF₅ K₃AlF₆ Na₃AlF₆ KAsF₆ LiAsF₆ NaAsF₆ HBF₄ KBF₄ LiBF₄ NaBF₄ RbBF₄ Ba(BF₄)₂ Ni(BF₄)₂ Pb(BF₄)₂ Sn(BF₄)₂ BaClF BaSiF₆ BaGeF₆ BrOF₃ BrO₂F CBrF₃ CBr₂F₂ CBr₃F CClF₃ CCl₂F₂ CCl₃F CFN CF₂O CF₃I CHF₃ CH₂F₂ CH₃F C₂Cl₃F₃ C₂H₃F C₆H₅F C₇H₅F₃ C₁₅F₃₃N ClFO₂ CrFO₄ CrF₂O₂ CsBF₄ NH₄F FNO FNO₂ FNO₃ KHF₂ NaHF₂ ThOF₂ NH₅F₂ F₂OS F₃OP F₃PS HPF₆ HSbF₆ KPF₆ KSbF₆ LiPF₆ NaPF₆ NaSbF₆ Na₂SiF₆ Na₂TiF₆ Na₂ZrF₆ TlPF₆ IOF₃ K₂NbF₇ K₂TaF₇ IO₃F
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Mangan(III) fluorida

Sintesis, struktur, dan reaksi

Struktur

Reaksi

Referensi

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Mangan(III) fluorida

Sintesis, struktur, dan reaksi

Struktur

Reaksi

Referensi

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